Product ID:127032, SULFURIC ACID STANDARD SOLUTION, 1.00N
MSDS Date:04/20/2001
FSC:6810
NIIN:01-456-4687
Status Code:A
MSDS Number: CLLDJ

HACH CO

5600 LINDBERGH DR
LOVELAND, CO 80538-8902
US

Emergency Phone: 303-623-5716

Info Phone: 970-669-3050/800-227-4224

Cage: 91224

KAMPI COMPONENTS CO., INC.

721 BRISTOL, PA 19007-3517 US

Telephone: 215-736-2000

Cage: 7Z016

DEMINERALIZEDWATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL NONE REPORTED

ACGIH TLV: NONE REPORTED

SULFURIC ACID

CAS: 7664-93-9

RTECS: WS5600000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

OTHER COMPONENT

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

LD50 LC50 Mixture:NONE GIEN FOR PRODUCT AS A WHOLE
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:EYE CONTACT: CAUSES EYE BURNS. SKIN
CONTACT: MAY CAUSE IRRITATION. SKIN ABSORPTION: NONE REPORTED.
TARGET ORGANS: NONE REPORTED. INGESTION: MAY CAUSE: IRRITATION OR
THE MOUTH AND ESOPHAGUS. TARGET ORG ANS: NONE REPORTED. INHALATION:
MAY CAUSE: RESPIRATORY TRACT IRRITATION, DIFFICULT BREATHING, MOUTH
SORENESS, TEETH EROSION. TARGET ORGANS: LUNGS. CHRONIC: CHRONIC
OVEREXPOSURE MAY CAUSE CANCER.
Explanation of Carcinogenicity:AN INGREDIENT OF THIS MIXTURE IS: IARC
GROUP 1: RECOGNIZED CARCINOGEN. SULFURIC ACID-THE IARC EVALUATION
WAS BASE ON EXPOSURE TO THE MIST OR VAPOR OF CONCENTRATED SULFURIC
ACID GENERATED DURING CHEMIC AL PROCESSES.
Effects of Overexposure:EYE CONTACT: CAUSES EYE BURNS. SKIN CONTACT:
MAY CAUSE IRRITATION. SKIN ABSORPTION: NONE REPORTED. TARGET
ORGANS: NONE REPORTED. INGESTION: MAY CAUSE: IRRITATION OR THE
MOUTH AND ESOPHAGUS. TARGET ORG ANS: NONE REPORTED. INHALATION: MAY
CAUSE: RESPIRATORY TRACT IRRITATION, DIFFICULT BREATHING, MOUTH
SORENESS, TEETH EROSION. TARGET ORGANS: LUNGS. CHRONIC: CHRONIC
OVEREXPOSURE MAY CAUSE CANCER.
Medical Cond Aggravated by Exposure:PRE-EXISTING: EYE CONDITIONS,
RESPIRATORY CONDITIONS.

First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH WATER FOR 15
MINUTES. CALL PHYSICIAN. SKIN CONTACT: WASH SKIN WITH PLENTY OF
WATER FOR 15 MINUTES. CALL PHYSICIAN IMMEDIATELY. INGESTION: DO NOT
INDUCE VOMITIN G. GIVE 1-2 GLASSES OF WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN IMMEDIATELY.
INHALATION: REMOVE TO FRESH AIR.

Flash Point Method:COC
Extinguishing Media:DRY CHEMICAL. DO NOT USE WATER.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING
APPARATUS PRESSURE-DEMAND AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:DURING A FIRE, CORROSIVE AND TOXIC GASES
MAY BE GENERATED BY THERMAL DECOMPOSTION.

Spill Release Procedures:COVER SPILLED MATERIAL WITH AN ALKALI, SUCH AS
SODA ASH OR SODIUM BICARBONATE. SCOOP UP SLURRY INTO A LARGE
BEAKER. ADJUST TO A PH BETWEEN 6 AND 9 WITH AN ALKALI, SUCH AS SODA
ASH OR SODIUM BICARBONAT E. DISPOSE OF MATERIAL IN AN E.P.A.
APPROVED HAZARDOUS WASTE FACILITY. DECONTAMINATE THE AREA OF THE
SPILL WITH A SOAP SOLUTION.
Neutralizing Agent:SODA ASH OR SODIUM BICARBONATE.

Handling and Storage Precautions:HANDLING: AVOID CONTACT WITH EYES. DO
NOT BREATHE MIST OR VAPORS. WASH THOROUGHLY AFTER HANDLING.
MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS
PRODUCT. STORAGE: KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
Other Precautions:EMPTY CONTAINERS: RINSE THREE TIMES WITN AN
APPROPRIATE SOLVENT. DISPOSE OF EMPTY CONTAINERS AS NORMAL TRASH.

Respiratory Protection:ADEQUATE VENTILATION.
Ventilation:ADEQUATE VENTILATION.
Protective Gloves:DISPOSABLE LATEX GLOVES.
Eye Protection:SAFETY GLASSES WITH TOP AND SIDE SHIELDS.
Other Protective Equipment:LAB COAT. HAVE A SAFETY SHOWER NEARBY.
Work Hygienic Practices:MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES
WHEN USING THIS PRODUCT. AVOID CONTACT WITH: EYES. DO NOT BREATHE;
MIST/VAPOR. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NO DATA PROVIDED BY MANUFACTURER

HCC:C1
Boiling Pt:=100.C, 212.F
Vapor Pres:ND
Vapor Density:ND
Spec Gravity:0.990
pH:<0.5
Evaporation Rate & Reference:0.56 (WATER=1)
Solubility in Water:MISCIBLE (WATER/ACID)
Appearance and Odor:CLEAR COLORLESS LIQUID, NO ODOR.
Corrosion Rate:1.16 IN/YR (STEEL)

Stability Indicator/Materials to Avoid:YES
CAUSTICS.
Stability Condition to Avoid:STABLE WHEN STORED UNDER PROPER
CONDITIONS. AVOID EXTREME TEMPERATURES, HEATING TO DECOMPOSITION..
Hazardous Decomposition Products:HEATING TO DECOMPOSITION RELEASES
TOXIC AND/OR CORROSIVE FUMES OF: SULFUR OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:WORK IN AN APPROVED FUME HOOD. DILUTE MATERIAL
WITH EXCESS WATER MAKING A WEAKER THAN 5% SOLUTION. ADJUST TO A PH
BETWEEN 6 AND 9 WITH AN ALKALI, SUCH AS SODA ASH OR SODIUM
BICARBONATE. OPEN COLD WATE R TAP COMPLETELY, SLOWLY POUR THE
REACTED MATERIAL TO THE DRAIN. ALLOW COLD WATER TO RUN FOR 5 MINUT
ES TO COMPLETELY FLUSH THE SYSTEM.

Toxicological Information:PRODUCT TOXICOLOGICAL DATA: LD50: NONE
REPORTED. LC50: NONE REPORTED. DERMAL TOXICITY DATA: NONE REPORTED.
SKIN AND EYE IRRITATION DATA: SLIGHT ERYTHEMA @ 3 MINUTES AND 1
HOUR AFTER APPLICATION. MUTAT ION DATA: NONE REPORTED. REPRODUCTIVE
EFFECTS: NONE REPORTED. INGREDIENT TOXICOLOGICAL DATA: SULFURIC
ACID: ORAL RAT LD50 = 2140 MG/KG; INHALATION RAT LC50 = 347 PPM/HR.

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Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:PRODUCT ECOLOGICAL INFORMATION: NO ECOLOGICAL DATA AVAILABLE
FOR THIS PRODUCT. INGREDIENT ECOLOGICAL INFORMATION: SULFURIC ACID:
THE 48-HOUR TLM IN FLOUNDER IS 100-300 PPM.

Transport Information:DOT PROPER SHIPPING NAME: CORROSIVE LIQUID,
ACIDIC, INORGANIC, N.O.S. (<10% SULPHURIC ACID IN SOLUTION); DOT
HAZARD CLASS: 8. DOT SUBSIDIARY RISK: NA. DOT ID NUMBER: UN3264.
DOT PACKING GROUP: III. IC AO PROPER SHIPPING NAME: CORROSIVE
LIQUID, ACIDIC, INORGANIC, N.O.S. (<10% SULPHURIC ACID IN
SOLUTION); ICAO HAZARD CLASS: 8. ICAO SUBSIDIARY RISK: NA. ICAO ID
NUMBER: UN3264. ICAO PACKING GROUP: III. IMO PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (<10% SULPHURIC ACID IN
SOLUTION); IMO HAZARD CLASS: 8. IMO SUBSIDIARY RISK: NA. IMO ID
NUMBER: UN3264. IMO PACKING GROUP: III.

SARA Title III Information:SARA TITLE III SECTION 311/312
CATEGORIZATION (40 CFR 370): IMMEDIATE 9ACUTE) HEALTH HAZARD,
DELAYED (CHRONIC) HEALTH HAZARD, REACTIVE. SARA TITLE III SECTION
313 (40 CFR 372): THIS PRODUCT CONTAINS A CHEMICAL(S) SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF SARA:
SULFURIC ACID. 302 EHS TPQ (40 CFR 355): SULFURIC ACID = 1000 LBS.
304 CERCLA RQ (40 CFR 302.4): SULFURIC ACID = 1000 LBS. 304 EHS RQ
(40 CFR 355): SULFURIC ACID = 1000 LBS.
Federal Regulatory Information:CLEAN WATER ACT (40 CFR 116.4): SULFURIC
ACID = RQ 1000 LBS. RCRA: CONTAINS RCRA REGULATED SUBSTANCES. SEE
DISPOSAL SECTION FOR EPA WASTE ID NUMBER. CPSC: NOT APPLICABLE. US
INVENTORY STATUS: ALL INGR EDIENTS IN THIS PRODUCT ARE LISTEDD ON
THE TSCA 8(B) INVENTORY (40 CFR 710). TSCA CAS NUMBER: NOT
APPLICABLE.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NO PROPOSITION
65 LISTED CHEMICALS ARE PRESENT IN THIS PRODUCT.